{"id":1610,"date":"2013-07-01T09:43:50","date_gmt":"2013-07-01T01:43:50","guid":{"rendered":"http:\/\/wp.kmu.edu.tw\/rd\/?p=1610"},"modified":"2013-07-04T12:44:42","modified_gmt":"2013-07-04T04:44:42","slug":"%e7%a0%94%e7%a9%b6%e6%96%b0%e7%9f%a5-6","status":"publish","type":"post","link":"https:\/\/wp.kmu.edu.tw\/rd\/archives\/1610","title":{"rendered":"\u7814\u7a76\u65b0\u77e5"},"content":{"rendered":"<p style=\"text-align: right\"><a href=\"http:\/\/wp.kmu.edu.tw\/rd\/archives\/1608\">\u56de\u7b2c0010\u671f\u4e3b\u9801<\/a><\/p>\n<h1><span style=\"font-size: x-large;color: #c10000\">\u4e00\u3001\u7814\u7a76\u65b0\u77e5<\/span><\/h1>\n<p><a name=\"ResNew1\"><\/a><\/p>\n<ul>\n<ul>\n<li>\n<h1><span style=\"color: #0000ff\">\u4ee5\u5149\u5316\u5b78\u9014\u5f91\u958b\u555f\u6c34\u6c27\u5316\u7528\u975e\u6676\u578b\u91d1\u5c6c\u6c27\u5316\u7269\u50ac\u5316\u5291\u4e4b\u88fd\u5099<br \/>\n\uff08\u672c\u6821\u91ab\u85e5\u66a8\u61c9\u7528\u5316\u5b78\u7cfb\u9673\u6cca\u4f59\u6559\u6388\u63d0\u4f9b\uff09<br \/>\n<\/span><\/h1>\n<p>\u6458\u81eaScience, Vol 340, 60-63, 2013. Photochemical Rout for Accessing Amorphous Metal Oxide Materials for Water Oxidation Catalysis<\/p>\n<p>\u6c2b\u6c23(hydrogen gas, H2)\u5c07\u662f\u672a\u4f86\u66ff\u4ee3\u77f3\u5316\u71c3\u6599\u4e4b\u91cd\u8981\u518d\u751f\u80fd\u6e90\u4e4b\u4e00\u3002\u773e\u6240\u5468\u77e5\uff0c\u6c2b\u6c23\u53ef\u85c9\u7531\u96fb\u89e3\u6c34\u800c\u751f\u6210\uff0c\u5176\u5404\u81ea\u96fb\u6975\u7684\u534a\u53cd\u61c9\u5982\u4e0b\u6240\u793a\uff1a<br \/>\nAnode reaction: 2H2O \u2192 O2 + 4H+ + 4e-E0 = -1.23 V (vs. NHE)<br \/>\nCathode reaction: 4H2O + 4e- \u2192 2H2 + 4OH-E0 = -0.83 V (vs. NHE)<br \/>\n\u6c2b\u6c23\u5728\u96fb\u89e3\u53cd\u61c9\u69fd\u7684\u9670\u6975(cathode)\u751f\u6210\u3002\u96fb\u89e3\u6c34\u7522\u751f\u6c2b\u6c23\u7684\u904e\u7a0b\u591a\u9700\u8981\u6975\u9ad8\u7684\u64cd\u4f5c\u96fb\u58d3\uff0c\u5176\u539f\u56e0\u537b\u4e0d\u5728\u9670\u6975\u7684\u6c2b\u6c23\u751f\u6210\u53cd\u61c9\uff0c\u800c\u662f\u56e0\u70ba\u967d\u6975(anode)\u4e0a\u6c34\u96fb\u89e3\u7522\u751f\u6c27\u6c23\u7684\u53cd\u61c9\u5728\u5316\u5b78\u52d5\u529b\u5b78\u4e0a\u662f\u4e00\u500b\u7de9\u6162\u7684\u53cd\u61c9\uff0c\u5373\u6240\u8b02\u53d7\u52d5\u529b\u5b78\u63a7\u5236\u7684\u53cd\u61c9\uff0c\u81f4\u4f7f\u967d\u6975\u53cd\u61c9\u9700\u8981\u6975\u9ad8\u7684\u904e\u96fb\u58d3(overvoltage)\u624d\u80fd\u5f97\u5230\u4e00\u5408\u7406\u7684\u53cd\u61c9\u96fb\u6d41\u3002\u7531\u65bc\u6c27\u5316\u9084\u539f\u53cd\u61c9\u662f\u4f34\u96a8\u767c\u751f\uff0c\u5728\u4e00\u96fb\u89e3\u69fd\u4e2d\u6574\u9ad4\u96fb\u6d41\u662f\u540c\u6642\u53d7\u967d\u6975\u53ca\u9670\u6975\u53cd\u61c9\u6240\u5f71\u97ff\uff0c\u7531\u65bc\u6c27\u6c23\u751f\u6210\u53cd\u61c9\u9650\u5236\u4e86\u53cd\u61c9\u96fb\u6d41\uff0c\u81f4\u4f7f\u96fb\u89e3\u6c34\u6642\u9700\u8981\u6975\u9ad8\u7684\u904e\u96fb\u58d3\uff0c\u52a0\u5287\u4e86\u80fd\u91cf\u7684\u6d88\u8017\u3002\u56e0\u6b64\uff0c\u767c\u5c55\u96fb\u89e3\u6c34\u4e4b\u6c27\u6c23\u751f\u6210\u7aef\u7684\u967d\u6975\u50ac\u5316\u5291\u662f\u76f8\u7576\u91cd\u8981\u7684\u7814\u7a76\u3002<br \/>\n\u76ee\u524d\u7528\u65bc\u6c34\u96fb\u89e3\u6c27\u5316\u7522\u751f\u6c27\u6c23\u7684\u967d\u6975\u6750\u6599\u591a\u70ba\u91d1\u5c6c\u6c27\u5316\u7269(metal oxides)\u96fb\u6975\u3002\u5176\u88fd\u4f5c\u591a\u63a1\u7528\u96fb\u6c88\u7a4d(electrodeposition)\u7684\u65b9\u5f0f\u5f62\u6210\u3002\u7136\u800c\uff0c\u96fb\u6c88\u7a4d\u6709\u8af8\u591a\u9650\u5236\uff0c\u9664\u7121\u6cd5\u9069\u7528\u65bc\u6240\u6709\u4e4b\u91d1\u5c6c\u6c27\u5316\u7269\u5916\uff0c\u4e5f\u672a\u898b\u591a\u91d1\u5c6c\u7d44\u6210\u4e4b\u6c27\u5316\u7269\u96fb\u6975\u4ee5\u96fb\u6c88\u7a4d\u65b9\u5f0f\u5f62\u6210\uff0c\u4e3b\u8981\u662f\u56e0\u70ba\u6c27\u5316\u7269\u6c88\u7a4d\u6642\u5c0d\u65bd\u4e88\u96fb\u4f4d\u7684\u65b9\u5f0f\u975e\u5e38\u654f\u611f\u3002\u70ba\u6b64\uff0c\u52a0\u62ff\u5927\u5361\u52a0\u5229\u5927\u5b78(University of Calgary, Canada)\u5316\u5b78\u7cfb\u8207\u5148\u9032\u592a\u967d\u80fd\u6750\u6599\u4e2d\u5fc3\u7684Prof. Curtis P. Berlinguette\u53caProf. Simon Trudel\u767c\u5c55\u4e86\u5229\u7528\u5149\u5316\u5b78\u53cd\u61c9\u7684\u65b9\u5f0f\u88fd\u5099\u975e\u6676\u578b\u91d1\u5c6c\u6c27\u5316\u7269\u96fb\u6975\u7528\u65bc\u6c34\u96fb\u89e3\u4e4b\u6c27\u5316\u53cd\u61c9\u3002\u8a31\u591a\u967d\u6975\u91d1\u5c6c\u6c27\u5316\u7269\u6750\u6599\u591a\u70ba\u6676\u9ad4\u7d50\u69cb\uff0c\u4f8b\u5982\u8d64\u9435\u7926\u7d50\u69cb\u4e4b\u6c27\u5316\u9435(hematite, \u03b1-Fe2O3)\uff0c\u4f46\u7814\u7a76\u767c\u73fe\u975e\u6676\u578b\u4e4b\u91d1\u5c6c\u6c27\u5316\u7269\u4ea6\u53ef\u5177\u6709\u76f8\u7576\u597d\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u56e0\u6b64\u9019\u5169\u4f4d\u52a0\u62ff\u5927\u6559\u6388\u6240\u767c\u5c55\u7684\u65b9\u6cd5\u5c07\u53ef\u65b9\u4fbf\u7684\u88fd\u4f5c\u55ae\u4e00\u91d1\u5c6c\u6c27\u5316\u7269\u6216\u591a\u91d1\u5c6c\u6c27\u5316\u7269\u96fb\u6975\u3002\u5176\u65b9\u6cd5\u662f\u5229\u7528\u524d\u8da8\u7269\uff0c\u4f8b\u5982iron(III) 2-ethylhexanoate\uff0c\u5c07\u5176\u5df1\u70f7(hexane)\u6eb6\u6db2\u4ee5\u65cb\u8f49\u5857\u4f48(spin-coating)\u7684\u65b9\u5f0f\u5f62\u6210\u8584\u819c\u65bc\u6c1f\u647b\u96dc\u6c27\u5316\u932b\u73bb\u7483\u96fb\u6975(fluorine-doped tin oxide)\u6216\u77fd\u6676\u5713\u4e0a\uff0c\u63a5\u8457\u518d\u4ee5184-nm\u4ee5\u53ca254-nm\u4e4b\u5149\u6ce2\u7167\u5c04\u5f62\u6210\u91d1\u5c6c\u6c27\u5316\u7269\u8584\u819c\uff0c\u6b64\u4e00\u65b9\u6cd5\u7a31\u70baphotochemical metal-organic deposition (PMOD)\u3002\u6240\u5f62\u6210\u7684\u8584\u819c\u5728\u4f4e\u6eab\u4e0b\u9032\u884c\u935b\u71d2\u5373\u53ef\u5f62\u6210\u91d1\u5c6c\u5747\u52fb\u5206\u4f48\u4e14\u7d50\u69cb\u7a69\u5b9a\u4e4b\u55ae\u4e00\u91d1\u5c6c\u6c27\u5316\u7269\u8584\u819c\u6216\u591a\u91d1\u5c6c\u6c27\u5316\u7269\u8584\u819c\u96fb\u6975\u3002\u9ad8\u6eab\u8655\u7406\u96d6\u80fd\u5f62\u6210\u6676\u9ad4\u6c27\u5316\u7269\u7d50\u69cb\uff0c\u4f46\u537b\u8b8a\u5f97\u5bb9\u6613\u5f62\u6210\u9f9c\u88c2\u7684\u8584\u819c\u3002PMOD\u65b9\u6cd5\u4e5f\u5177\u6709\u80fd\u7cbe\u78ba\u63a7\u5236\u8584\u819c\u7d44\u6210\u7684\u7279\u9ede\u3002\u6b64\u4e00\u65b9\u6cd5\u6240\u88fd\u4f5c\u51fa\u7684\u975e\u6676\u578b\u6c27\u5316\u9435\u96fb\u6975(a-Fe2O3)\u5728\u96fb\u89e3\u6c34\u751f\u6210\u6c27\u6c23\u7684\u50ac\u5316\u6548\u80fd\u4e0a\u51cc\u99d5\u65bchematite\u3002\u800c\u975e\u6676\u578b\u591a\u91cd\u91d1\u5c6c\u6c27\u5316\u7269a-Fe100-y-zCoyNizOx\u7684\u50ac\u5316\u80fd\u529b\u5247\u8207\u76ee\u524d\u5546\u696d\u96fb\u89e3\u53cd\u61c9\u5668\u6240\u4f7f\u7528\u7684\u8cb4\u91d1\u5c6c\u6c27\u5316\u7269\u96fb\u6975\u76f8\u7576\u3002<br \/>\nProf. Curtis P. Berlinguette\u53caProf. Simon Trudel\u767c\u5c55\u7684PMOD\u65b9\u6cd5\u53ef\u4e0d\u53d7\u9650\u7684\u5728\u5c0e\u96fb\u57fa\u7248\u4e0a\u65bc\u4f4e\u6eab\u4e0b\u5f62\u6210\u5404\u7a2e\u975e\u6676\u578b\u91d1\u5c6c\u6c27\u5316\u7269\u3002\u9019\u4e9b\u6c27\u5316\u7269\u7684\u50ac\u5316\u6d3b\u6027\u4e0d\u4e9e\u65bc\u6676\u9ad4\u7d50\u69cb\u7684\u91d1\u5c6c\u6c27\u5316\u7269\u96fb\u6975\u4ee5\u53ca\u5546\u696d\u904b\u8f49\u6240\u4f7f\u7528\u7684\u8cb4\u91d1\u5c6c\u6c27\u5316\u7269\u96fb\u6975\u3002\u6b64\u4e00\u65b9\u6cd5\u5c0d\u964d\u4f4e\u88fd\u4f5c\u6210\u672c\u4e26\u63d0\u9ad8\u50ac\u5316\u6d3b\u6027\u4e0a\uff0c\u5c07\u6709\u91cd\u5927\u7684\u5f71\u97ff\u8207\u8ca2\u737b\u3002<\/li>\n<\/ul>\n<\/ul>\n<p style=\"text-align: right\"><a href=\"http:\/\/wp.kmu.edu.tw\/rd\/archives\/1608\">\u56de\u7b2c0010\u671f\u4e3b\u9801<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u56de\u7b2c0010\u671f\u4e3b\u9801 \u4e00\u3001\u7814\u7a76\u65b0\u77e5 \u4ee5\u5149\u5316\u5b78\u9014\u5f91\u958b\u555f\u6c34\u6c27\u5316\u7528\u975e\u6676\u578b\u91d1\u5c6c\u6c27\u5316\u7269\u50ac\u5316\u5291 &hellip; <a href=\"https:\/\/wp.kmu.edu.tw\/rd\/archives\/1610\">\u95b1\u8b80\u5168\u6587 <span class=\"meta-nav\">&rarr;<\/span><\/a><\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_exactmetrics_skip_tracking":false,"_exactmetrics_sitenote_active":false,"_exactmetrics_sitenote_note":"","_exactmetrics_sitenote_category":0,"footnotes":""},"categories":[18],"tags":[],"class_list":["post-1610","post","type-post","status-publish","format-standard","hentry","category-18"],"_links":{"self":[{"href":"https:\/\/wp.kmu.edu.tw\/rd\/wp-json\/wp\/v2\/posts\/1610","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/wp.kmu.edu.tw\/rd\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/wp.kmu.edu.tw\/rd\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/wp.kmu.edu.tw\/rd\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/wp.kmu.edu.tw\/rd\/wp-json\/wp\/v2\/comments?post=1610"}],"version-history":[{"count":8,"href":"https:\/\/wp.kmu.edu.tw\/rd\/wp-json\/wp\/v2\/posts\/1610\/revisions"}],"predecessor-version":[{"id":1665,"href":"https:\/\/wp.kmu.edu.tw\/rd\/wp-json\/wp\/v2\/posts\/1610\/revisions\/1665"}],"wp:attachment":[{"href":"https:\/\/wp.kmu.edu.tw\/rd\/wp-json\/wp\/v2\/media?parent=1610"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/wp.kmu.edu.tw\/rd\/wp-json\/wp\/v2\/categories?post=1610"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/wp.kmu.edu.tw\/rd\/wp-json\/wp\/v2\/tags?post=1610"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}