{"id":31,"date":"2013-04-18T15:02:53","date_gmt":"2013-04-18T07:02:53","guid":{"rendered":"http:\/\/wp.kmu.edu.tw\/sodiohsu\/?page_id=31"},"modified":"2019-03-21T23:09:17","modified_gmt":"2019-03-21T15:09:17","slug":"research-of-sodio-hsu-lab","status":"publish","type":"page","link":"https:\/\/wp.kmu.edu.tw\/sodiohsu\/sodio-hsu\/research-of-sodio-hsu-lab\/","title":{"rendered":"Research (\u7814\u7a76\u9818\u57df)"},"content":{"rendered":"

<\/p>\n

Sodio Lab offers several international Master or PhD student positions dedicated to the study of bio-inspired and metallo-supramolecular chemistry. <\/span><\/strong><\/p>\n

Sodio lab<\/span>‘s rese<\/span>arch interests focus on the synthesis of tradition metal coordination complexes for using in bioinorganic and supramolecular chemistry study. Our research topic can be divided into three broad themes: (1) the synthesis of bio-inspired copper(I)-NO2<\/sub> complexes containing poly-nitrogen and phosphine ligands, (2) the <\/span>synthesis and structural study of copper(I) clusters as a copper transfer protein modeling compound, (3)<\/span> the rational synthesis <\/span>and structural study of iron\u2013sulfur core {Cp2<\/sub>Fe2<\/sub>(m<\/span>-SEt)2<\/sub>} complexes<\/span>. <\/span><\/a><\/span><\/p>\n

<\/p>\n

1.\u00a0\u00a0\u00a0\u00a0 <\/span><\/span><\/b>Synthesis of bio-inspired copper(I)-NO2<\/sub> complexes containing poly-nitrogen and phosphine ligands<\/span><\/b><\/p>\n

\"electronic<\/a><\/span><\/p>\n

Scheme view of HC(3,5-R2<\/sub>Pz)3<\/sub> and [HB(3,5-R2<\/sub>Pz)3<\/sub>]–<\/sup> ligands. <\/span><\/p>\n

\u00a0<\/span><\/p>\n

\"TPCuNO2\"<\/a><\/span><\/p>\n

\u00a0<\/span><\/p>\n

Complex [L3<\/b>Cu(NO2<\/sub>)(H2<\/sub>O)](PPN) represents the first example of a solid state nitrous acid intermediate (Cu-NO2<\/sub>H) analog. <\/span><\/p>\n

\u00a0\"P1\"<\/a>\"P2\"<\/a><\/span><\/p>\n

ORTEP representation of the <\/span>molecular<\/span> structure<\/span>s<\/span> of <\/span>copper(I) phosphine-ether complexes with NO2<\/sub><\/span>–<\/span><\/sup> binding<\/span>.<\/span><\/p>\n


\n<\/span><\/p>\n

2.\u00a0\u00a0\u00a0\u00a0 <\/span><\/span><\/b>The <\/span><\/b>synthesis and structural study of copper(I) clusters as a copper transfer protein modeling compound<\/span><\/b><\/p>\n

\"Ligand<\/a><\/span><\/p>\n

Representation of the dithiolato ligands used in this study<\/span><\/p>\n

\u00a0\"L3Cu5\"<\/a><\/span><\/p>\n

3.\u00a0\u00a0\u00a0\u00a0 <\/span><\/span><\/b>The rational synthesis <\/span><\/b>and structural study of iron\u2013sulfur core {Cp2<\/sub>Fe2<\/sub>(m<\/span>-SEt)2<\/sub>} complexes<\/span><\/b><\/p>\n

\"Fe4\"<\/a><\/p>\n

\"Iron\"<\/a><\/p>\n

Representation of the Redox Control Cavity Modulation of the <\/span>Rectangular Tetranuclear Iron<\/span>-Thiolate-Aryldiisocyanide<\/span>Complex<\/span>.<\/span><\/p>\n

\u00a0<\/span><\/p>\n","protected":false},"excerpt":{"rendered":"

Sodio Lab offers several international M … \u95b1\u8b80\u5168\u6587 →<\/span><\/a><\/p>\n","protected":false},"author":11,"featured_media":134,"parent":2,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"_exactmetrics_skip_tracking":false,"_exactmetrics_sitenote_active":false,"_exactmetrics_sitenote_note":"","_exactmetrics_sitenote_category":0,"footnotes":""},"class_list":["post-31","page","type-page","status-publish","has-post-thumbnail","hentry"],"_links":{"self":[{"href":"https:\/\/wp.kmu.edu.tw\/sodiohsu\/wp-json\/wp\/v2\/pages\/31","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/wp.kmu.edu.tw\/sodiohsu\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/wp.kmu.edu.tw\/sodiohsu\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/wp.kmu.edu.tw\/sodiohsu\/wp-json\/wp\/v2\/users\/11"}],"replies":[{"embeddable":true,"href":"https:\/\/wp.kmu.edu.tw\/sodiohsu\/wp-json\/wp\/v2\/comments?post=31"}],"version-history":[{"count":19,"href":"https:\/\/wp.kmu.edu.tw\/sodiohsu\/wp-json\/wp\/v2\/pages\/31\/revisions"}],"predecessor-version":[{"id":132,"href":"https:\/\/wp.kmu.edu.tw\/sodiohsu\/wp-json\/wp\/v2\/pages\/31\/revisions\/132"}],"up":[{"embeddable":true,"href":"https:\/\/wp.kmu.edu.tw\/sodiohsu\/wp-json\/wp\/v2\/pages\/2"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/wp.kmu.edu.tw\/sodiohsu\/wp-json\/wp\/v2\/media\/134"}],"wp:attachment":[{"href":"https:\/\/wp.kmu.edu.tw\/sodiohsu\/wp-json\/wp\/v2\/media?parent=31"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}